p-Methylaminophenol-Sulfat (Metol)
p-Methylaminophenol-Sulfat (Metol)
p-Methylaminophenol Sulfate (Metol)
CAS-Nr.:
55-55-0
COA & MSDS:
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1. Basic Identification Information

ParameterEnglish Specification/Value
IUPAC Namebis(4-(methylamino)phenol); sulfuric acid (also: 4-(Methylamino)phenol sulfate (2:1) salt)
Common Name(s)p-Methylaminophenol Sulfate; Metol; N-methyl-p-aminophenol sulfate; Bis(4-hydroxy-N-methylanilinium) sulfate; 4-Methylaminophenol hemisulfate
CAS Registry Number55-55-0
EC/EINECS Number200-232-0
Molecular Formula(C₇H₁₀NO)₂·H₂SO₄ (or C₁₄H₂₀N₂O₆S)
Molecular Weight344.38 g/mol
Chemical ClassAminophenol sulfate salt; oxidative hair dye coupler; photographic developing agent; reducing agent
Related Compound4-Aminophenol (CAS 123-30-8) (parent compound without methyl substitution; higher toxicity and sensitization risk)

2. Physicochemical Properties

Property CategorySpecific ParameterSpecification/Value
Structural FeaturesFunctional GroupsTwo molecules of 4-(methylamino)phenol (each with -OH at C1 and -NHCH₃ at C4) protonated and bound to one sulfate ion (SO₄²⁻); para-substitution enables stable hydrogen bonding and dye coupling
Physical AppearanceState & ColorWhite to off-white crystalline powder; turns pale pink/brown on prolonged air exposure (slow oxidation); faint phenolic/methylamine odor
Melting Point240–245 °C (decomposes; lit.)
Boiling PointDecomposes before boiling (releases SO₃ and methylaminophenol vapors above 280 °C)
Density (25 °C)1.43 g/cm³ (crystalline form)
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