5,5-dimethylimidazolidine-2,4-dione (DMH)
5,5-dimethylimidazolidine-2,4-dione (DMH)
5,5-dimethylimidazolidine-2,4-dione (DMH)
CAS NO.:
77-71-4
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Product Introduction

1. Basic Identification Information

ParameterEnglish Specification/Value
IUPAC Name5,5-Dimethylimidazolidine-2,4-dione (also: 5,5-Dimethyl-2,4-imidazolidinedione)
Common Name(s)5,5-Dimethylhydantoin; DMH; Dimethylhydantoin; Hydantoin, 5,5-dimethyl-; Dantoin DMH
CAS Registry Number77-71-4
EC/EINECS Number200-51-3
Molecular FormulaC₅H₈N₂O₂
Molecular Weight128.13 g/mol
Chemical ClassCyclic urea; imidazolidinedione derivative; organic synthesis intermediate; polymer building block
Related CompoundHydantoin (CAS 461-72-3) (parent compound without methyl substitutions; higher solubility but lower thermal stability)

2. Physicochemical Properties

Property CategorySpecific ParameterSpecification/Value
Structural FeaturesFunctional GroupsCyclic structure with two carbonyl groups (C=O at C2 and C4), two NH groups (at N1 and N3), and two methyl groups (-CH₃) at C5; symmetric dimethyl substitution enhances thermal stability
Physical AppearanceState & ColorWhite to off-white crystalline powder; odorless or faint urea-like odor; bitter taste
Melting Point174–177 °C (lit., decomposes above 280 °C)
Boiling PointDecomposes before boiling (releases CO₂ and methylamine vapors above 280 °C)
Density (25 °C)1.10 ± 0.1 g/cm³ (crystalline form)
SolubilityPolar SolventsSlightly soluble in water (≈2 g/100 mL at 25 °C; increases to 10 g/100 mL at 80 °C); soluble in methanol (15 g/100 mL), ethanol (8 g/100 mL), and dimethylformamide (25 g/100 mL)
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