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1. Basic Identification Information
| Parameter | English Specification/Value |
|---|---|
| IUPAC Name | 5,5-Dimethylimidazolidine-2,4-dione (also: 5,5-Dimethyl-2,4-imidazolidinedione) |
| Common Name(s) | 5,5-Dimethylhydantoin; DMH; Dimethylhydantoin; Hydantoin, 5,5-dimethyl-; Dantoin DMH |
| CAS Registry Number | 77-71-4 |
| EC/EINECS Number | 200-51-3 |
| Molecular Formula | C₅H₈N₂O₂ |
| Molecular Weight | 128.13 g/mol |
| Chemical Class | Cyclic urea; imidazolidinedione derivative; organic synthesis intermediate; polymer building block |
| Related Compound | Hydantoin (CAS 461-72-3) (parent compound without methyl substitutions; higher solubility but lower thermal stability) |
2. Physicochemical Properties
| Property Category | Specific Parameter | Specification/Value |
|---|---|---|
| Structural Features | Functional Groups | Cyclic structure with two carbonyl groups (C=O at C2 and C4), two NH groups (at N1 and N3), and two methyl groups (-CH₃) at C5; symmetric dimethyl substitution enhances thermal stability |
| Physical Appearance | State & Color | White to off-white crystalline powder; odorless or faint urea-like odor; bitter taste |
| Melting Point | 174–177 °C (lit., decomposes above 280 °C) | |
| Boiling Point | Decomposes before boiling (releases CO₂ and methylamine vapors above 280 °C) | |
| Density (25 °C) | 1.10 ± 0.1 g/cm³ (crystalline form) | |
| Solubility | Polar Solvents | Slightly soluble in water (≈2 g/100 mL at 25 °C; increases to 10 g/100 mL at 80 °C); soluble in methanol (15 g/100 mL), ethanol (8 g/100 mL), and dimethylformamide (25 g/100 mL) |



